Heroes that served as an apprentice to a villain at any point of their lives. These heroes may have been forced to be an apprentice to a villain under some certain circumstances, not aware that their mentors are villains or simply lost their way. When they find out their mentor is evil, or when they realize the path they are on is the wrong one, the hero abandons their master, which will most likely lead to a confrontation between teacher and student.
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A
- Ace Riders
- Adam Kane
- Agira
- Ahsoka Tano
- Ai Hayasaka
- Ajest Jedgar F. Roguepalace
- Akame
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- Alain (Pokémon)
- Alexia Midgar
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- Almatea Atismata
- Amane Fuuma
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- Amu Ishikawa
- Anakin Skywalker
- Angelene
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- Anne Boonchuy
- Annette
- Anti Spirit Team
- Ardyn Izunia
- Arisu Sakayanagi
- Artemisia Bell Ashcroft
- Asatsuki Shiga
- Ashen Wolves
- Ashley Ashra
- Asuka Koukawa
- Aunn Komano
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- Ayase Ayatsuji
- Azuma Kamimura
B
C
-
- Calvin "Freckle" McMurray
- Caroline and Justine
- Cat Noir
- Chaldea Security Organization
- Charlie Morningstar
- Chen (Touhou)
- Chevreuse
- Chitaru Namatame
- Chiyuri Kitashirakawa
- Chloé d'Apchier
- Cho-Hakkaimon
- Class 3-E
- Clownpiece
- Copy of SpongeBob SquarePants
- Count Dooku
- Craig Tinker
- Crimson Squad
- Cruz Ramirez
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- Cyan Sung-Sun
- Cyberwarp
- Cécile Croomy
D
E
-
- Edith (Kamen Rider Ghost)
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- Eiko Aizawa
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- Eleanor Hume
- Elise (Bungo Stray Dogs)
- Elite Seven
- Elizabeth (Gintama)
- Elliot Nightray
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- Emonga
- Enbi Yuuki
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- Enrique
- Esdeath
- Esther Rosenthal
- Euphyllia Magenta
- Execution Division Apprentice
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-
G
H
- Hailmar
- Hajime Hinata/Izuru Kamukura
- Hajime Kashimo
- Hana Kurusu
- Hanzō Academy
- Harold Hutchins
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- Haru Ichinose
- Hell Knight Ingrid
- Hell Knight Lina
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- Hibana
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-
- Hikari & Hibiki
- Hildagard Schlievogt
- Hina Farrow
- Hitomi Uzaki
- Homer Simpson
- Horobi
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-
I
J
- J (Murder Drones)
- Jack Swagger
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- Jade (Mortal Kombat)
- Jail Murdoch
- Jan Suk
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-
- Jeralt Reus Einser
- Jericho (The Seven Deadly Sins)
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- Jetstream Sam
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-
- Jin Kazama (Tekken)
- Jin Kisaragi
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- Jing Yuan
- Juniper Woods
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K
- K.O.
- Kaede Akamatsu
- Kamen Rider Club
- Kamen Rider Mage
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- Kanako Yasaka
- Karyl
- Katara
- Kawaro Tekkain
- Kayo Hinazuki
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- Khadgar
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- Kitana
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-
- Knothead and Splinter
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- Koakuma
- Korra
- Korsica
- Kosetsu Minobe
- Kotal Kahn
- Kourin Takanagi
- Kujou Sara
- Kung Lao
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- Kurenai Shinganji